iCarly - Season 3 Episode 10 iSaved Your Life
Overview: Carly, unaware of an oncoming taco truck, is pushed aside by Freddie, who subsequently gets hit. Carly, grateful to Freddie for saving her life, develops an attraction towards him. However, Freddie thinks that this attraction stems from his actions, and not himself, so the two break up but agree that if the whole "hero" thing wears off that if Carly still feels attracted to him they'll try the relationship again. Meanwhile, Sam and Spencer engage in an intense game of assassin.